Mallika first appeared in some TV Commercials with Amitabh Bachchan for BPL and Shahrukh Khan for Santro. She also came in some music video of Nirmal Pandey and Surjit Bindrakhia. She debuted in film Jeena Sirf Merre Liye.
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Then Mallika starred in film Khwahish in year 2003, and Murder in year 2004. She got nomination for Best Actress at the Zee Cine Awards for the film Murder.
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It was one of the biggest hit of the year. In year 2005 she came in a Chinese film, The Myth with Jackie Chan.
Then in year 2006 she starred in film Pyaar Ke Side Effects which went moderate on box office. In year 2007 she came in a song Mayya Mayya of film Guru. She also played a guest role in film Aap Ka Suroor – The Real Love Story for which she charged Rs 15 million for 10 Minute appearance.
Later that year she came in film Welcome which was also a hit on box office. Then in year 2008 she did two films Ugly aur Pagli and Maan Gaye Mughal-e-Azam which got flop on box office. In year 2009 she starred a Hollywood film Hisss.
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Then later she also did another Hollywood comedy film Politics of Love.